Facile synthesis of temperature-sensitive ABA triblock copolymers by dispersion RAFT polymerization

被引:7
|
作者
Serkhacheva, Natalia S. [1 ]
Chernikova, Elena V. [2 ]
Balashov, Michael S. [1 ]
Prokopov, Nikolay I. [1 ]
Toms, Roman V. [1 ]
机构
[1] MIREA Russian Technol Univ, MV Lomonosov Inst Fine Chem Technol, Moscow 119571, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
关键词
reversible addition-fragmentation chain transfer (RAFT); RAFT polymerization; dispersion polymerization; self-assembly; block copolymers; temperature-sensitive polymers; FRAGMENTATION CHAIN TRANSFER;
D O I
10.1016/j.mencom.2020.11.014
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The dispersion RAFT polymerization was applied for the first time to synthesize the well-defined ABA triblock copolymer core-shell nanoparticles of temperature-sensitive poly(N-isopropylacrylamide-co-acrylic acid)-block-poly(n-butyl acrylate)-block-poly(N-isopropylacrylamide-co-acrylic acid) and poly(n-butyl acrylate-co-N-isopropylacrylamide)-blockpoly(n-butyl acrylate)-block-poly(n-butyl acrylate-co-N-isopropylacrylamide).
引用
收藏
页码:731 / 733
页数:3
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