Revisiting the Role of Polysulfides in Lithium-Sulfur Batteries

被引：542

作者：

Li, Gaoran ^{[1
,2
]}

Wang, Shun ^{[1
]}

Zhang, Yining ^{[2
]}

Li, Matthew ^{[2
]}

Chen, Zhongwei ^{[2
]}

Lu, Jun ^{[3
]}

机构：

[1] Wenzhou Univ, Nanomat & Chem Key Lab, Wenzhou 325027, Peoples R China

[2] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada

[3] Argonne Natl Lab, Chem Sci & Engn Div, 9700 S Cass Ave, Argonne, IL 60439 USA

来源：

ADVANCED MATERIALS | 2018年 / 30卷 / 22期

基金：

加拿大自然科学与工程研究理事会; 中国国家自然科学基金;

关键词：

energy density; lithium-sulfur batteries; polysulfide management; polysulfides; HIGH-ENERGY-DENSITY; LI-S BATTERIES; SPARINGLY SOLVATING ELECTROLYTES; PARTIALLY FLUORINATED ETHER; HIGH-PERFORMANCE; METAL ANODE; CONDUCTIVE POLYMER; CATHODE MATERIAL; LIQUID ELECTROLYTE; ELEMENTAL-SULFUR;

D O I：

10.1002/adma.201705590

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intermediate polysulfides (S-n, where n = 2-8) play a critical role in both mechanistic understanding and performance improvement of lithium-sulfur batteries. The rational management of polysulfides is of profound significance for high-efficiency sulfur electrochemistry. Here, the key roles of polysulfides are discussed, with regard to their status, behavior, and their correspondingimpact on the lithium-sulfur system. Two schools of thoughts for polysulfide management are proposed, their advantages and disadvantages are compared, and future developments are discussed.

引用

页数：19

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