Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes

被引:11
|
作者
Yamamoto, T
Yasuda, T
Kobayashi, K
Yamaguchi, I
Koizumi, T
Ishii, D
Nakagawa, M
Mashiko, Y
Shimizu, N
机构
[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Denki Kagaku Kogyo KK, Organ Mat Res Ctr, Niigata 9490393, Japan
[3] Denki Kagaku Kogyo KK, Elect Mat Res Ctr, Gunma 3778520, Japan
关键词
D O I
10.1246/bcsj.79.498
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It is shown that industrially available 2,3-dichloro-1,3-butadiene is a useful starting material for the synthesis of 2,3-diaryl-1,3-butadienes. Ni(II)-catalyzed cross-coupling reaction of 2,3-dichloro-1,3-butadiene with ArMgBr (Ar = 2-thienyl, phenyl, 4-dodecyloxyphenyl, and 4-fluorophenyl) gives the corresponding 2,3-diaryl-1,3-butadienes in good yields.
引用
收藏
页码:498 / 500
页数:3
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