Clean and effective utilization of moldy peel as a biomass waste resource in the gasification process of petroleum coke

被引:5
|
作者
Zhou, Shichao [1 ,2 ]
Chen, Zhengjie [1 ,2 ,3 ]
Ma, Wenhui [1 ,2 ,3 ]
机构
[1] Kunming Univ Sci & Technol, Fac Met & Energy Engn, Kunming 650093, Yunnan, Peoples R China
[2] Kunming Univ Sci & Technol, State Key Lab Complex Nonferrous Met Resources C, Kunming 650093, Yunnan, Peoples R China
[3] Kunming Univ Sci & Technol, Natl Engn Lab Vacuum Met, Kunming 650093, Yunnan, Peoples R China
基金
中国国家自然科学基金;
关键词
SILICON PRODUCTION; CARBON-DIOXIDE; HEAT-RECOVERY; KINETICS; ENERGY; COAL; PARAMETERS; BEHAVIORS; PYROLYSIS; BLENDS;
D O I
10.1039/d0se01162b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We conducted an exploratory study on the characteristics and applications of carbonaceous materials prepared using different types of biomass and petroleum coke (PC). The strengthening mechanism was analyzed based on the outcomes of the experimental results we obtained from micro-analytical methods, such as Fourier-transform infrared spectroscopy, Raman spectroscopy and scanning electron microscopy. The results indicated that within the scope of the experiment, when mixed with petroleum coke, moldy orange peel (M-OP) played a prominent strengthening role. The strengthening manifests itself as a 30-70 degrees C reduction in T-max. Notably, the reaction rate at T-max and the activation energy were markedly reduced as the biomass ratio increased from 20% to 50%. The increase in activity may also be related to the fermentation of OP. Microorganisms produce enzymes, causing the enzymatic hydrolysis of the fibrous part of OP to produce a large number of small molecules, increase the specific surface area, and expose more carboxyl, hydroxyl and other active groups. This study may provide new insights into expanding the application of biomass and have important implications for developing different types of biomass as carbon materials in production systems to promote clean, efficient production.
引用
收藏
页码:6096 / 6104
页数:9
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