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A Novel 3D Twofold Zn(II) Coordination Polymer Constructed by Mixed Flexible Ligands: Synthesis, Crystal Structure and Fluorescence Property

被引：15
|
作者：
Li Pei-Xuan [1 ]
Lu Jiu-Fu [1 ,2 ]
机构：
[1] Xian Univ Sci & Technol, Sch Energy Sci & Engn, Xian 710054, Peoples R China
[2] Shaanxi Sci Tech Univ, Coll Chem & Environm Sci, Shaanxi Prov Key Lab Catalyt Fdn & Applicat, Hanzhong 723001, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 02期
关键词：
Zn(II) coordination polymer; twofold interpenetrating; photoluminescence property; BIS(IMIDAZOLE) LIGANDS; MAGNETIC-PROPERTIES; CO-LIGANDS; LUMINESCENT PROPERTY; FRAMEWORK; 1,3-BIP; ACID; 2D;
D O I：
10.14102/j.cnki.0254-5861.2011-1054
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Zn(II) coordination polymer, {[Zn(1,3-bip)(oba)]center dot 0.5H(2)O}(n) (1), 1,3-bip = 1,3-bis(imidazole) propane, H(2)oba = 4,4'-oxybis(benzoate)), have been synthesized and characterized by single-crystal X-ray diffraction, powder XRD, FTIR, TGA and elemental analysis techniques. The single-crystal X-ray diffraction reveals that complex 1 shows a 3D -> 3D twofold interpenetrating network that can be described as a 4-connected uninodal net with (6(5).8) topology. In addition, the photoluminescence property of complex 1 was also investigated at room temperature.
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页码：303 / 309
页数：7
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