Development of a one-pot method for the homologation of aldehydes to carboxylic acids

被引：22
|
作者：
McNulty, James [1 ]
Das, Priyabrata [1 ]
机构：
[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada
来源：
TETRAHEDRON | 2009年 / 65卷 / 37期
基金：
加拿大自然科学与工程研究理事会;
关键词：
ONE-CARBON HOMOLOGATION; PETERSON OLEFINATION; EFFICIENT METHOD; DERIVATIVES; ELONGATION; CONVENIENT; CONVERSION; CHLORIDES; KETONES; SYSTEM;
D O I：
10.1016/j.tet.2009.07.032
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly efficient method is described for the one-carbon homologation of aldehydes to carboxylic acid derivatives employing the reaction of a 1,1 -bis-dimethylphosphonate derivative with the aldehyde and controlled acid hydrolysis of the derived alpha-phosphonoenamine intermediate. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7794 / 7800
页数：7
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