Gold@Prussian blue analogue core-shell nanoheterostructures: their optical and magnetic properties

被引:13
|
作者
Maurin-Pasturel, Guillaume [1 ]
Mamontova, Ekaterina [1 ]
Palacios, Maria A. [1 ]
Long, Jerome [1 ]
Allouche, Joachim [2 ]
Dupin, Jean-Charles [2 ]
Guari, Yannick [1 ]
Larionova, Joulia [1 ]
机构
[1] Univ Montpellier, Inst Charles Gerhardt Montpellier, UMR 5253, ENSCM,CNRS,Ingn Mol & Nanoobjets, Pl E Bataillon, F-34095 Montpellier 5, France
[2] Univ Pau & Pays Adour, Inst Sci Analyt & Physicochim Environm & Mat, Technopole Hilioparc Pau Pyrennees, UMR 5253, 2 Ave President Pierre Angot, F-64053 Pau 09, France
关键词
METAL-ORGANIC FRAMEWORKS; POROUS COORDINATION POLYMERS; NANOPARTICLES; HETEROSTRUCTURES; CYANIDE; DEPOSITION; SPECTRA;
D O I
10.1039/c9dt00141g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Au@Prussian-Blue Analogue (PBA) shell nanoheterostructures are multifunctional nano-objects combining optical properties (surface plasmon resonance) of the Au core and magnetic properties of the PBA shell. We report in this article a series of new Au core@PBA shell nano-objects with different PBA shells: Au@K/Co/[Fe-II(CN)(6)] (2) and Au@K/Ni/[Cr-III(CN)(6)]:[Fe-II(CN)(6)] (3) single PBA shell, as well as Au@K/Ni/[Fe-II(CN)(6)]@K/Ni/[Fe-III(CN)(6)] (4) double PBA shell and Au@K/Ni/[Fe-II(CN)(6)]@K/Ni/[Fe-III(CN)(6)]@K/Ni/[Cr-III(CN)(6)] (5) triple PBA shell systems. The position and intensity of the Au SPR band, as well as the magnetic behaviour of the nanoheterostructures, are strongly affected by the shell composition and its thickness.
引用
收藏
页码:6205 / 6216
页数:12
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