Performance evaluation of anode-supported aim Gd0.1Ce0.9O1.95 cell with electrospun La0.6Sr0.4Co0.2Fe0.8O3-δ-Gd0.1Ce0.9O1.95 cathode

被引:23
|
作者
Lee, Jin Goo [1 ]
Lee, Chan Min [2 ]
Park, Myeong Geun [1 ]
Jung, Sang-Jin [3 ]
Shul, Yong Gun [1 ]
机构
[1] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
[2] Kyushu Univ, Interdisciplinary Grad Sch Engn Sci, Dept Mol & Mat Sci, Kasuga, Fukuoka 8168580, Japan
[3] Korea Maritime Univ, LINC, Pusan 606791, South Korea
关键词
Electrospinning; Solid oxide fuel cells; Cathode; Lanthanum strontium cobalt ferrite; Gadolinia-doped ceria; OXYGEN REDUCTION; SOFC; NANOFIBERS;
D O I
10.1016/j.electacta.2013.06.091
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A cathode performance is considered as a key factor to enhance the power efficiency of intermediate temperature solid oxide fuel cells (IT-SOFCs). In order to improve the cathode performance, La0.6Sr0.4Co0.2Fe0.8O3-delta-Gd0.1Ce0.9O1.95 (LSCF-GDC) cathode is fabricated by electrospinning method. The three-dimensional fiber network cathode has high porosity, continuous pathway for charge transfer and increased triple phase boundary sites (TPB). The electrospun cathode is applied to Ni-GDC anode-supported Gd0.9Ce0.9O1.95 cell. The electrical properties of the electrospun LSCF-GDC cathode are compared with the conventional LSCF-GDC powder cathode. The polarization resistance and maximum power density of the cell with the electrospun cathode are about 0.08 Omega cm(2) and 0.85 W cm(-2) at 650 degrees C, respectively. The power density of the cell with the electrospun cathode is approximately two times higher than 0.45 W cm(-2) (at 650 degrees C) of the cell with the conventional LSCF-GDC cathode. This result demonstrates that the application of the electrospun LSCF-GDC cathode can be a promising method for enhancing the electrical performance of an anode-supported GDC cell at intermediate temperatures. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:356 / 360
页数:5
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