Carbonyl(8-hydroxyquinolinato-κ2N,O)[tris-(2,3,4,5,6-pentafluorophenyl) phosphine-κP]-rhodium(I)

被引:4
|
作者
van Rensburg, J. Marthinus Janse [1 ]
Roodt, Andreas [1 ]
机构
[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa
关键词
D O I
10.1107/S1600536806040190
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Molecules of the title compound, [Rh(C9H6NO)(C18F15P)-(CO)], pack in a tail-to-tail fashion, with an intermolecular ligand-to-ligand pi-pi stacking distance of 3.399 (8) angstrom. The effective cone angle (Theta(E)) for the phosphine ligand is 163 degrees. The bite angle of the bidentate oxine ligand is 80.77 (10)degrees and the Rh-P bond length is 2.2145 (11) angstrom.
引用
收藏
页码:M2981 / M2983
页数:3
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