Alkali Phosphonate Metal-Organic Frameworks

被引：26

作者：

Maares, Maria ^{[1
]}

Ayhan, M. Menaf ^{[2
]}

Yu, Kai B. ^{[3
]}

Yazaydin, A. Ozgur ^{[3
]}

Harmandar, Keyser ^{[2
]}

Haase, Hajo ^{[1
]}

Beckmann, Jens ^{[4
]}

Zorlu, Yunus ^{[2
]}

Yuecesan, Gundog ^{[1
]}

机构：

[1] Tech Univ Berlin, Lebensmittelchem & Toxikol, Gustav Meyer Allee 25, D-13355 Berlin, Germany

[2] Gebze Tech Univ, Dept Chem, TR-41400 Kocaeli, Turkey

[3] UCL, Dept Chem Engn, London WC1E 7JE, England

[4] Univ Bremen, Inst Anorgan Chem & Kristallog, Leobener Str, D-28359 Bremen, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2019年 / 25卷 / 48期

关键词：

alkali-phosphonate; metal-organic frameworks; porphyrin; thermal stability; toxicology; TETRAPHOSPHONIC ACIDS; CRYSTALLINE; MOFS;

D O I：

10.1002/chem.201902207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new family of porous metal-organic frameworks (MOFs), namely alkali phosphonate MOFs, is reported. [Na2Cu(H(4)TPPA)].(NH2(CH3)(2))(2) (GTUB-1) was synthesized using the tetratopic 5,10,15,20-tetrakis[p-phenylphosphonic acid] porphyrin (H-8-TPPA) linker with planar X-shaped geometrical core. GTUB-1 is composed of rectangular void channels with BET surface area of 697 m(2) g(-1). GTUB-1 exhibits exceptional thermal stability. The toxicity analysis of the (H-8-TPPA) linker indicates that it is well tolerated by an intestinal cell line, suggesting its suitability for creating phosphonate MOFs for biological applications.

引用

页码：11214 / 11217

页数：4

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