Bonding configurations of cyclopropane on Ni(111) and Cu(111) surfaces

被引：9
|
作者：
Wang, J [1 ]
McBreen, PH [1 ]
机构：
[1] UNIV LAVAL,DEPT CHIM,QUEBEC CITY,PQ G1K 7P4,CANADA
来源：
SURFACE SCIENCE | 1997年 / 392卷 / 1-3期
基金：
加拿大自然科学与工程研究理事会;
关键词：
alkanes; carbides; chemisorption; infrared absorption spectroscopy; molybdenum carbide; polycrystalline surfaces;
D O I：
10.1016/S0039-6028(97)00702-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Reflection-absorbtion FTIR spectra were recorded for the interaction of cyclopropane with Ni(lll) and Cu(lll) surfaces. The very different spectra observed for the two systems permit a clear differentiation of the adsorption geometries adopted on both metals. Cyclopropane lies flat on Cu(lll), whereas the interaction with Ni(lll) is preferentially with one edge of the molecule. The bonding interactions at the origin of the observed geometries are discussed. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：L45 / L50
页数：6
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