Charge-transfer processes at the interface between hydrophobic ionic liquid and water

被引：72

作者：

Samec, Zdenek ^{[1
]}

Langmaier, Jan ^{[1
]}

Kakiuchi, Takashi ^{[2
]}

机构：

[1] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, Vvi, CR-18223 Prague 8, Czech Republic

[2] Kyoto Univ, Dept Energy & Hydrocarbon Chem, Grad Sch Engn, Kyoto 6158510, Japan

来源：

PURE AND APPLIED CHEMISTRY | 2009年 / 81卷 / 08期

关键词：

ionic liquids; liquid-liquid interfaces; two-phase liquid systems; ion transfer; electron transfer; standard Gibbs energy of ion transfer; polarized potential window; TEMPERATURE MOLTEN-SALT; AQUEOUS-ELECTROLYTE SOLUTION; NONPOLARIZED INTERFACE; POLARIZED INTERFACE; CYCLIC VOLTAMMETRY; THIN-LAYER; PHASE; EXTRACTION; SOLVATION; POLARIZABILITY;

D O I：

10.1351/PAC-CON-08-08-36

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article provides a brief review of theoretical and methodological concepts in the area of the charge-transfer processes at the interface between a hydrophobic ionic liquid (IL) and an electrolyte solution in water (W). Electrochemical methods of study of the W|IL interfaces are described, current experimental problems are indicated, and the most important experimental results are summarized. The relevance of electrochemistry at the W|IL interfaces to the extraction behavior of ILs is outlined.

引用

页码：1473 / 1488

页数：16

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