Ionic Telomerization of 1-Chloro-2,3-epoxypropane with Allyl Alcohol and Properties of Products Obtained

被引:0
|
作者
Kerimov, A. Kh. [1 ]
Orudzheva, A. T. [1 ]
Mamedova, Kh. A. [1 ]
Alieva, U. A. [1 ]
机构
[1] Natl Acad Sci Azerbaijan, Inst Polymer Mat, Sumgayit, Azerbaijan
关键词
Allyl Alcohol; Telomerization; Glycidyl Ether; Chlorohydrin; Ether Alcohol;
D O I
10.1134/S1070427213090084
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Ionic telomerization of 1-chloro-2,3-epoxypropane with allyl alcohol in the presence of boron trifluoride etherate as a route to halogenated epoxy oligoethers was studied. Selective chlorination or bromination of the intermediate oligo(chlorohydrin), followed by dehydrochlorination (epoxidation) of the intermediate oligohalohydrins with NaOH, was performed. The synthesized products are efficient as active diluents for a compound based on ED-20 resin.
引用
收藏
页码:1364 / 1369
页数:6
相关论文
共 50 条