Oxidative coupling of amines and ketones by combined vanadium- and organocatalysis

被引：177
|
作者：
Sud, Abhishek [1 ]
Sureshkumar, Devarajulu [1 ]
Klussmann, Martin [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim An Der Ruhr, Germany
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 22期
关键词：
SP(3) C-H; CARBON BOND FORMATION; ASYMMETRIC MANNICH REACTIONS; TERTIARY-AMINES; MOLECULAR-OXYGEN; SODIUM-CYANIDE; NITROGEN ATOM; ACTIVATION; CYANATION; ADJACENT;
D O I：
10.1039/b901282f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The combination of vanadium- and organocatalysis allows for the direct oxidative coupling of cyclic tertiary amines with non-activated ketones without the need for preformed leaving groups.
引用
收藏
页码：3169 / 3171
页数：3
相关论文
共 50 条
  • [11] OXIDATIVE COUPLING OF PHENOLS USING VANADIUM TETRACHLORIDE AND VANADIUM OXYTRICHLORIDE
    CARRICK, WL
    KARAPINKA, GL
    KWIATKOWSKI, GT
    JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (08): : 2388 - +
  • [12] π-Conjugated polymeric phthalocyanine for the oxidative coupling of amines
    Wu, Haihong
    Cao, Yanwei
    Zhu, Gangli
    Zeng, Dehong
    Zhu, Xiang
    Du, Jimin
    He, Lin
    CHEMICAL COMMUNICATIONS, 2020, 56 (25) : 3637 - 3640
  • [13] Coupling of Methyl Ketones and Primary or Secondary Amines Leading to α-Ketoamides
    Wei, Wei
    Shao, Ying
    Hu, Huayou
    Zhang, Feng
    Zhang, Chao
    Xu, Yuan
    Wan, Xiaobing
    JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (17): : 7157 - 7165
  • [14] Synthesis of Amines by Oxidative Coupling of Benzylamine over a Vanadium-Nitrogen Co-doped Porous Carbon Catalyst
    Wu Xiao-Xue
    Qi Yan-Yan
    Wang Ying-Yi
    Wang Li
    Tu Gao-Mei
    Fu Yang-He
    Chen De-Li
    Zhu Wei-Dong
    Zhang Fu-Min
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2022, 38 (06) : 1049 - 1058
  • [15] Atomically Dispersed Vanadium Sites Anchored on N-Doped Porous Carbon for the Efficient Oxidative Coupling of Amines to Imines
    Xu, Qionghao
    Feng, Binbin
    Ye, Chunlin
    Fu, Yanghe
    Chen, De-Li
    Zhang, Fumin
    Zhang, Jiangwei
    Zhu, Weidong
    ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (13) : 15168 - 15177
  • [16] Copper/Manganese Cocatalyzed Oxidative Coupling of Vinylarenes with Ketones
    Lan, Xing-Wang
    Wang, Nai-Xing
    Zhang, Wei
    Wen, Jia-Long
    Bai, Cui-Bing
    Xing, Yalan
    Li, Yi-He
    ORGANIC LETTERS, 2015, 17 (18) : 4460 - 4463
  • [17] Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
    Levashov, Andrey S.
    Aksenov, Nicolai A.
    Aksenova, Inna V.
    Konshin, Valeriy V.
    NEW JOURNAL OF CHEMISTRY, 2017, 41 (16) : 8297 - 8304
  • [18] OXIDATIVE COUPLING AND CROSS-COUPLING OF ACETYLENIC AMINES AND ACETYLENIC CARBINOLS
    HENNION, GF
    PRICE, L
    JOURNAL OF ORGANIC CHEMISTRY, 1962, 27 (05): : 1587 - &
  • [19] Azobisisobutyronitrile Initiated Aerobic Oxidative Transformation of Amines: Coupling of Primary Amines and Cyanation of Tertiary Amines
    Liu, Lianghui
    Wang, Zikuan
    Fu, Xuefeng
    Yan, Chun-Hua
    ORGANIC LETTERS, 2012, 14 (22) : 5692 - 5695
  • [20] Electrochemical oxidative annulation of amines and aldehydes or ketones to synthesize polysubstituted pyrroles
    Gao, Xinlong
    Wang, Pan
    Wang, Qingqing
    Chen, Jingting
    Lei, Aiwen
    GREEN CHEMISTRY, 2019, 21 (18) : 4941 - 4945
12345