Pd/C-catalyzed transfer reduction of aryl chlorides with sodium formate in water

被引：37
|
作者：
Arcadi, A
Cerichelli, G
Chiarini, M
Vico, R
Zorzan, D
机构：
[1] Univ Aquila, Dipartimento Chim Ingn Chim & Mat, I-67010 Coppito, AQ, Italy
[2] Univ Teramo, Dipartimento Sci Alimenti, I-64023 Mosciano Stn, TE, Italy
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 2004卷 / 16期
关键词：
reductive dechlorination; palladium; catalysis; sodium formate; aryl chlorides;
D O I：
10.1002/ejoc.200400258
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Sodium formate catalytic transfer reduction, in the presence of palladium on carbon, accomplishes not only the rapid dehalogenation of aromatic chlorocarbons in water at room temperature, but also the reduction of the aromatic moieties to alicyclic rings at 100degreesC. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
引用
收藏
页码：3404 / 3407
页数：4
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