Hydrothermal synthesis, crystal structures of two new transition metal coordination chain polymers with mixed ligands

被引:30
|
作者
He, X [1 ]
Lu, CZ [1 ]
Yan, Y [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
基金
中国国家自然科学基金;
关键词
transition metal complex; mixed ligands; photoluminescence; NLO;
D O I
10.1016/j.inoche.2004.04.024
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Hydrothermal reactions of fumaric acid, 1,10-phenanthroline or 2,2'-bipyridine and transition metal cations gave rise to two complexes, [Zn(Hmal)(1,10-phen)(H2O)](n) (1) and [Cu(Hmal)(2,2'-bipy)](n).3nH(2)O (2) (malic acid=H(3)mal). The photoluminescence spectrum and the interesting second-order non-linear optical (NLO) property for compound 1 have been studied. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:851 / 853
页数:3
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