In situ characterisation of peroxybenzimidic acid by FT-Raman and ATR/FTIR spectroscopy

被引:13
|
作者
Vacque, V
Dupuy, N
Sombret, B
Huvenne, JP
Legrand, P
机构
[1] Lasir-CNRS, Univ. des Sci. et Techniques de L.
关键词
ATR spectroscopy; peroxybenzimidic acid; Raman spectroscopy;
D O I
10.1016/S0022-2860(96)09334-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
To elucidate the mechanism of the reaction of benzonitrile and hydrogen peroxide in alkaline medium, an experimental study was carried out by FT-Raman and ATR/FTIR. We were able to identify the intermediate peroxycarboximidic acid by assigning number of characteristic vibrations like nu C=N or nu O-O.
引用
收藏
页码:165 / 174
页数:10
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