Integrated production of biodiesel and bioethanol from sweet potato

被引:36
|
作者
Virginio e Silva, Joab Oliveira [1 ]
Almeida, Manuel Fonseca [1 ]
Alvim-Ferraz, Maria da Conceicao [2 ]
Dias, Joana Maia [1 ]
机构
[1] Univ Porto, Fac Engn, Dept Engn Met & Mat, LEPABE, R Dr Roberto Frias, P-4200465 Porto, Portugal
[2] Univ Porto, Fac Engn, Dept Engn Quim, LEPABE, R Dr Roberto Frias, P-4200465 Porto, Portugal
关键词
Bioethanol; Sweet potato; Biodiesel; Ethanolysis; ETHANOL-PRODUCTION; VEGETABLE-OILS; SUNFLOWER OIL; ETHYL-ESTERS; TRANSESTERIFICATION; FEEDSTOCK; FERMENTATION; OPTIMIZATION; PERFORMANCE; HYDROGEN;
D O I
10.1016/j.renene.2017.07.052
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In the present study, the production of sweet potato bioethanol was conducted at a small industrial plant in Brazil and integrated in biodiesel production through ethanolysis. The specific objectives were: (i) monitor bioethanol production at a small industrial plant, considering production yield; (ii) study the ethanolysis of sunflower oil using sweet potato bioethanol with different grades (98, 99 and 99.4 degrees GL), with focus on biodiesel yield and purity. Bioethanol was produced under the following conditions: Sweet potato dilution in water (1:1 in wt.%); enzymatic hydrolysis with alpha-amylase (90 degrees C) and glucoamylase (60 degrees C) enzymes (700 mL/t); and, fermentation (30 degrees C) with saccharomyces cerevisiae (3.3 kg/t). Ethanolysis was performed as follows: 6:1 ethanol:oil molar ratio; 1.0 wt% NaOH; 45 degrees C; 1 h. The average yield of bioethanol was 161.4 L/t, corresponding to 10 598 L/ha. Biodiesel synthesis using bioethanol of different grades showed that both the yield and purity of the product increased with the grade of the ethanol used, with values ranging from 63 to 83 wt%, and 50 to 94 wt% for yield and purity, respectively. Results show that a high alcohol grade is required to make viable integrated production of biodiesel and bioethanol. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:114 / 120
页数:7
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