Improving stability of perovskite solar cells using fullerene-polymer composite electron transport layer

被引:9
|
作者
Elnaggar, Mohamed M. [1 ,2 ,3 ]
Frolova, Lyubov A. [1 ]
Gordeeva, Alexandra M. [1 ]
Ustinova, Marina, I [1 ,4 ]
Laurenzen, Hannah [5 ]
Akkuratov, Alexander, V [1 ]
Nikitenko, Sergey L. [1 ]
Solov'eva, Elena A. [6 ]
Luchkin, Sergey Yu [4 ]
Fedotov, Yury S. [6 ]
Tsarev, Sergey A. [4 ]
Dremova, Nadezhda N. [1 ]
Stevenson, Keith J. [4 ]
Bredikhin, Sergey, I [6 ]
Olthof, Selina [5 ]
Aldoshin, Sergey M. [1 ]
Troshin, Pavel A. [1 ,7 ]
机构
[1] Russian Acad Sci IPCP RAS, Inst Problems Chem Phys, Semenov Prospect 1, Chernogolovka 141432, Moscow Region, Russia
[2] Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moscow Region, Russia
[3] Tanta Univ, Fac Sci, Dept Phys, Tanta 31512, Egypt
[4] Skolkovo Inst Sci & Technol, Moscow 121205, Russia
[5] Univ Cologne, Dept Chem, Greinstr 4-6, D-50939 Cologne, Germany
[6] RAS, Inst Solid State Phys, Chernogolovka, Russia
[7] Silesian Tech Univ, Fac Chem, Strzody 9, PL-44100 Gliwice, Poland
基金
俄罗斯科学基金会;
关键词
Perovskite solar cells; Conjugated polymers; Polymer; fullerene blends; Charge transport materials; P-i-n solar cell architecture; PERFORMANCE; EFFICIENT; MOBILITY;
D O I
10.1016/j.synthmet.2022.117028
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Perovskite solar cells (PSCs) have attracted significant attention due to their high efficiency and potential for low-cost manufacturing, but their commercialization is strongly impeded by low operational stability. The engineering of charge-transport layer materials have been recognized as an effective strategy to improve both stability and performance of PSCs. Here, we introduce a pyrrolo[3,4-c]pyrrole-1,4-dione-based n-type copolymer as an electron transport material for perovskite solar cells. Using a composite of this polymer with the fullerene derivative [60]PCBM delivered an efficiency of 16.4% and enabled long-term operational stability of p-i-n perovskite solar cells.
引用
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页数:6
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