Improving stability of perovskite solar cells using fullerene-polymer composite electron transport layer

被引：9

作者：

Elnaggar, Mohamed M. ^{[1
,2
,3
]}

Frolova, Lyubov A. ^{[1
]}

Gordeeva, Alexandra M. ^{[1
]}

Ustinova, Marina, I ^{[1
,4
]}

Laurenzen, Hannah ^{[5
]}

Akkuratov, Alexander, V ^{[1
]}

Nikitenko, Sergey L. ^{[1
]}

Solov'eva, Elena A. ^{[6
]}

Luchkin, Sergey Yu ^{[4
]}

Fedotov, Yury S. ^{[6
]}

Tsarev, Sergey A. ^{[4
]}

Dremova, Nadezhda N. ^{[1
]}

Stevenson, Keith J. ^{[4
]}

Bredikhin, Sergey, I ^{[6
]}

Olthof, Selina ^{[5
]}

Aldoshin, Sergey M. ^{[1
]}

Troshin, Pavel A. ^{[1
,7
]}

机构：

[1] Russian Acad Sci IPCP RAS, Inst Problems Chem Phys, Semenov Prospect 1, Chernogolovka 141432, Moscow Region, Russia

[2] Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moscow Region, Russia

[3] Tanta Univ, Fac Sci, Dept Phys, Tanta 31512, Egypt

[4] Skolkovo Inst Sci & Technol, Moscow 121205, Russia

[5] Univ Cologne, Dept Chem, Greinstr 4-6, D-50939 Cologne, Germany

[6] RAS, Inst Solid State Phys, Chernogolovka, Russia

[7] Silesian Tech Univ, Fac Chem, Strzody 9, PL-44100 Gliwice, Poland

来源：

SYNTHETIC METALS | 2022年 / 286卷

基金：

俄罗斯科学基金会;

关键词：

Perovskite solar cells; Conjugated polymers; Polymer; fullerene blends; Charge transport materials; P-i-n solar cell architecture; PERFORMANCE; EFFICIENT; MOBILITY;

D O I：

10.1016/j.synthmet.2022.117028

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Perovskite solar cells (PSCs) have attracted significant attention due to their high efficiency and potential for low-cost manufacturing, but their commercialization is strongly impeded by low operational stability. The engineering of charge-transport layer materials have been recognized as an effective strategy to improve both stability and performance of PSCs. Here, we introduce a pyrrolo[3,4-c]pyrrole-1,4-dione-based n-type copolymer as an electron transport material for perovskite solar cells. Using a composite of this polymer with the fullerene derivative [60]PCBM delivered an efficiency of 16.4% and enabled long-term operational stability of p-i-n perovskite solar cells.

引用

页数：6

共 50 条

[1] Molecular Engineering of the Fullerene-Based Electron Transport Layer Materials for Improving Ambient Stability of Perovskite Solar Cells
Elnaggar, Mohamed
Elshobaki, Moneim
Mumyatov, Alexander
Luchkin, Sergey Yu
Dremova, Nadezhda N.
Stevenson, Keith J.
Troshin, Pavel A.
[J]. SOLAR RRL, 2019, 3 (09):
[2] Interfacial defects passivation using fullerene-polymer mixing layer for planar-structure perovskite solar cells with negligible hysteresis
Hu, Xiaofei
Wang, Huaxin
Wang, Ming
Zang, Zhigang
[J]. SOLAR ENERGY, 2020, 206 (206) : 816 - 825
[3] Hybrid Fullerene-Based Electron Transport Layers Improving the Thermal Stability of Perovskite Solar Cells
Li, Shu-Hui
Xing, Zhou
Wu, Bao-Shan
Chen, Zuo-Chang
Yao, Yang-Rong
Tian, Han-Rui
Li, Meng-Fan
Yun, Da-Qin
Deng, Lin-Long
Xie, Su-Yuan
Huang, Rong-Bin
Zheng, Lan-Sun
[J]. ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (18) : 20733 - 20740
[4] Hydrophilic Fullerene Derivative Doping in Active Layer and Electron Transport Layer for Enhancing Oxygen Stability of Perovskite Solar Cells
Xu, Guiying
Wang, Shuhui
Bi, Pengqing
Chen, Haiyang
Zhang, Moyao
Xue, Rongming
Hao, Xiaotao
Wang, Zhaokui
Li, Yaowen
Li, Yongfang
[J]. SOLAR RRL, 2020, 4 (02):
[5] Stability enhancement of inverted perovskite solar cells using LiF in electron transport layer
Tan, Dawei
Zhang, Xuejing
Liu, Xiao
Zhang, Hongmei
Ma, Dongge
[J]. ORGANIC ELECTRONICS, 2020, 80
[6] Role of fullerene electron transport layer on the morphology and optoelectronic properties of perovskite solar cells
Upama, Mushfika Baishakhi
Elumalai, Naveen Kumar
Mahmud, Md Arafat
Wang, Dian
Haque, Faiazul
Goncales, Vinicius R.
Gooding, J. Justin
Wright, Matthew
Xu, Cheng
Uddin, Ashraf
[J]. ORGANIC ELECTRONICS, 2017, 50 : 279 - 289
[7] Improving the Performances of Perovskite Solar Cells via Modification of Electron Transport Layer
Jiang, Mao
Niu, Qiaoli
Tang, Xiao
Zhang, Heyi
Xu, Haowen
Huang, Wentao
Yao, Jizhong
Yan, Buyi
Xia, Ruidong
[J]. POLYMERS, 2019, 11 (01)
[8] Evaporable Indano[60]fullerene Ketone for the Electron Transport Layer of Inverted Perovskite Solar Cells
Matsuo, Yutaka
Ishikawa, Soma
Amada, Hirofumi
Yokoyama, Kento
Shui, Qing-jun
Huda, Miftakhul
Ueoka, Naoki
Lin, Hao-Sheng
[J]. CHEMISTRY LETTERS, 2023, 52 (08) : 685 - 687
[9] High Performance Planar Heterojunction Perovskite Solar Cells with Fullerene Derivatives as the Electron Transport Layer
Liu, Chang
Wang, Kai
Du, Pengcheng
Meng, Tianyu
Yu, Xinfei
Cheng, Stephen Z. D.
Gong, Xiong
[J]. ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (02) : 1153 - 1159
[10] Pyridine-Functionalized Fullerene Electron Transport Layer for Efficient Planar Perovskite Solar Cells
Liu, Hao-Ran
Li, Shu-Hui
Deng, Lin-Long
Wang, Ze-Yu
Xing, Zhou
Rong, Xian
Tian, Han-Rui
Li, Xin
Xie, Su-Yuan
Huang, Rong-Bin
Zheng, Lan-Sun
[J]. ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (27) : 23982 - 23989

← 1 2 3 4 5 →