Improving stability of perovskite solar cells using fullerene-polymer composite electron transport layer

被引：9

作者：

Elnaggar, Mohamed M. ^{[1
,2
,3
]}

Frolova, Lyubov A. ^{[1
]}

Gordeeva, Alexandra M. ^{[1
]}

Ustinova, Marina, I ^{[1
,4
]}

Laurenzen, Hannah ^{[5
]}

Akkuratov, Alexander, V ^{[1
]}

Nikitenko, Sergey L. ^{[1
]}

Solov'eva, Elena A. ^{[6
]}

Luchkin, Sergey Yu ^{[4
]}

Fedotov, Yury S. ^{[6
]}

Tsarev, Sergey A. ^{[4
]}

Dremova, Nadezhda N. ^{[1
]}

Stevenson, Keith J. ^{[4
]}

Bredikhin, Sergey, I ^{[6
]}

Olthof, Selina ^{[5
]}

Aldoshin, Sergey M. ^{[1
]}

Troshin, Pavel A. ^{[1
,7
]}

机构：

[1] Russian Acad Sci IPCP RAS, Inst Problems Chem Phys, Semenov Prospect 1, Chernogolovka 141432, Moscow Region, Russia

[2] Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moscow Region, Russia

[3] Tanta Univ, Fac Sci, Dept Phys, Tanta 31512, Egypt

[4] Skolkovo Inst Sci & Technol, Moscow 121205, Russia

[5] Univ Cologne, Dept Chem, Greinstr 4-6, D-50939 Cologne, Germany

[6] RAS, Inst Solid State Phys, Chernogolovka, Russia

[7] Silesian Tech Univ, Fac Chem, Strzody 9, PL-44100 Gliwice, Poland

来源：

SYNTHETIC METALS | 2022年 / 286卷

基金：

俄罗斯科学基金会;

关键词：

Perovskite solar cells; Conjugated polymers; Polymer; fullerene blends; Charge transport materials; P-i-n solar cell architecture; PERFORMANCE; EFFICIENT; MOBILITY;

D O I：

10.1016/j.synthmet.2022.117028

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Perovskite solar cells (PSCs) have attracted significant attention due to their high efficiency and potential for low-cost manufacturing, but their commercialization is strongly impeded by low operational stability. The engineering of charge-transport layer materials have been recognized as an effective strategy to improve both stability and performance of PSCs. Here, we introduce a pyrrolo[3,4-c]pyrrole-1,4-dione-based n-type copolymer as an electron transport material for perovskite solar cells. Using a composite of this polymer with the fullerene derivative [60]PCBM delivered an efficiency of 16.4% and enabled long-term operational stability of p-i-n perovskite solar cells.

引用

页数：6

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