Copper-Catalyzed Oxidative C-O Bond Formation of 2-Acyl Phenols and 1,3-Dicarbonyl Compounds with Ethers: Direct Access to Phenol Esters and Enol Esters

被引：24

作者：

Park, Jihye ^{[1
]}

Han, Sang Hoon ^{[1
]}

Sharma, Satyasheel ^{[1
]}

Han, Sangil ^{[1
]}

Shin, Youngmi ^{[1
]}

Mishra, Neeraj Kumar ^{[1
]}

Kwak, Jong Hwan ^{[1
]}

Lee, Cheong Hoon ^{[1
]}

Lee, Jeongmi ^{[1
]}

Kim, In Su ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Sch Pharm, Suwon 440746, South Korea

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 10期

基金：

新加坡国家研究基金会;

关键词：

TERT-BUTYL HYDROPEROXIDE; DECARBOXYLATIVE ACYLATION; PRIMARY ALCOHOLS; H BONDS; OXOCARBOXYLIC ACIDS; BENZYLIC OXIDATION; ALLYLIC OXIDATION; NITROGEN ATOM; ESTERIFICATION; ALDEHYDES;

D O I：

10.1021/jo500576x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A copper-catalyzed oxidative coupling of 2-carbonyl-substituted phenols and 1,3-dicarbonyl compounds with a wide range of dibenzyl or dialkyl ethers is described. This protocol provides an efficient preparation of phenol esters and enol esters in good yields with high chemoselectivity. This method represents an alternative protocol for classical esterification reactions.

引用

页码：4735 / 4742

页数：8

共 18 条

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