Double complex salts [Rh(NH3)5Cl]2[MCl6]Cl2 (M = Re, Os):: Synthesis and crystal structure

被引：0
|
作者：
Yusenko, KV
Gromilov, SA
Korol'kov, IV
Baidina, IA
Romanenko, GV
Korenev, SV
机构：
[1] Novosibirsk State Univ, Novosibirsk 630090, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Int Tomog Ctr, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 04期
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Double complex salts of composition [Rh(NH3)(5)Cl](2)[MCl6]Cl-2, where M = Re(IV) or Os(IV), were prepared and characterized. All phases are isostructural to previously described [Rh(NH3)(5)Cl](2)[MCl6]Cl-2, where M = Pt(IV) or Ir(IV). Single-crystal X-ray diffraction experiments were carried out; crystal structures were refined. The thermolysis products obtained under various atmospheres were studied.
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页码：511 / 516
页数：6
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