Effect of Functionalized SWCNTs on Microstructure of PP-g-MA/OMMT/f-SWCNTs Nanocomposite

被引:2
|
作者
Gao, Yao [1 ]
Wang, Yong [1 ]
Shi, Jing [1 ]
Zhu, Shibu [1 ]
Bao, Yanling [1 ]
Bai, Hongwei [1 ]
Li, Yanli [1 ]
机构
[1] SW Jiaotong Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Adv Technol Mat, Chengdu 610031, Peoples R China
基金
中国国家自然科学基金;
关键词
microstructure; PP-g-MA/OMMT/f-SWCNTs; crystallization behavior; interaction; HIGH-DENSITY POLYETHYLENE; MULTIWALL CARBON NANOTUBES; NONISOTHERMAL CRYSTALLIZATION; ELECTRICAL-CONDUCTIVITY; MECHANICAL-PROPERTIES; BEHAVIOR; CLAY; NUCLEATION; POLY(ETHYLENE-TEREPHTHALATE); GELATION/CRYSTALLIZATION;
D O I
10.1002/app.29304
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The aim of this work was to study the effect of functionalized single-walled carbon nanotubes (f-SWCNTs) on the microstructure of PP-g-MA/organic modified montmorillonite (OMMT)/f-SWCNTs ternary, nanocomposite. Pristine SWCNTs were chemically modified by maleic anhydride to improve,e the interaction between PP-g-MA and nanotubes. The dispersion states of OMMT in the different nanocomposites were investigated by wide angle X-ray diffraction. The morphologies scanning of the nanocomposites were characterized by electron microscopy. Crystallization behaviors of nanocomposites were studied through differential scanning calorimetry and polarizing optical microscopy. Different than the PP-g-MA/OMMT binary nanocomposite, in which the OMMT is mainly in all exfoliated state, the ternary PP-g-MA/OMMT/f-SWCNTs nanocomposite exhibits mostly intercalated OMMT. Furthermore, in the ternary nanocomposite, the crystallization of polymer is mainly induced by f-SWCNTs rather than by OMMT. (C) 2009 Wiley Periodicals, Inc, J Appl Polym in Sci 112: 2413-2424, 2009
引用
收藏
页码:2413 / 2424
页数:12
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