Synthetic approaches to asymmetric phthalocyanines and their analogues

被引:69
|
作者
Nemykin, Victor N. [1 ]
Dudkin, Semyon V. [1 ]
Dumoulin, Fabienne [2 ]
Hirel, Catherine [2 ]
Gurek, Ayse Gul [2 ]
Ahsen, Vefa [2 ]
机构
[1] Univ Minnesota, Dept Chem & Biochem, 1039 Univ Dr, Duluth, MN 55812 USA
[2] Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey
基金
美国国家科学基金会;
关键词
Asymmetric phthalocyanines and their analogues; subphthalocyanine; substituted phthalonitriles; synthesis; DIELS-ALDER REACTIONS; DONOR-ACCEPTOR PHTHALOCYANINE; NONLINEAR-OPTICAL PROPERTIES; SPECTROSCOPIC PROPERTIES; ELECTROCHEMICAL PROPERTIES; BINUCLEAR PHTHALOCYANINES; PHOTODYNAMIC THERAPY; SECO-PORPHYRAZINES; UNSYMMETRICAL PHTHALOCYANINE; ZINC PHTHALOCYANINE;
D O I
10.3998/ark.5550190.p008.412
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review summarizes synthetic strategies for the preparation of asymmetric phthalocyanines and their analogues. Cross-condensation between two phthalonitrile components, cross-condensation between one phthalonitrile and one non-nitrile component, targeted synthesis of AABB-type compounds, the subphthalocyanine ring-expansion method, as well as post-modification approaches on pre-formed symmetric and asymmetric systems, are discussed. Methodologies for targeted preparation of specific types of asymmetric phthalocyanines and their analogues are also briefly overviewed.
引用
收藏
页码:142 / 204
页数:63
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