Solvothermal Synthesis and Crystal Structure of K2CdSnS4

被引：0
|
作者：
Baiyin Meng-He [1 ,2 ]
Gang Gang [1 ]
Naren Ji-Ru-Ga [1 ]
机构：
[1] Inner Mongolia Normal Univ, Coll Chem & Environm Sci, Hohhot 010022, Peoples R China
[2] Key Lab Phys & Chem Funct Mat, Hohhot 010022, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 30卷 / 02期
关键词：
solvothermal synthesis; crystal structure; quaternary thiostannate; optical property; OPEN-FRAMEWORK SULFIDE; FLUX SYNTHESIS; THIOSTANNATES; CHALCOGENIDES; RB; CS; ADAMANTANE; DISCRETE; IONS; MN2+;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Layered K2CdSnS4 (1) was synthesized solvothermally and characterized by X-ray single crystal diffraction. The crystals belong to the space group C2/c, with a=1.102 1(5) nm, b=1.103 0(5) nm, c=1.515 1(10) nm, alpha=90 degrees, P=100.416 (12)degrees, gamma=90 degrees, V=1.811 4 (17) nm(3), Z=8, D-e=3.209 g.cm(-3), M-r=437.60 mu=6.853 mm(-1), F(000)=1 600, lambda=0.071 073 nm, and the final R=0.104 2 and wR =0.200 8 for all observed reflections. The compound is comprised of sheets with adamantane-like [Cd2Sn2S10](8-) units. UV-Vis reflectance spectrum of compound 1 reveals that 1 is a semiconductor with a band gap of 2.2 eV. CCDC: 424763.
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页码：405 / 410
页数：6
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