Exciton diffusion and dissociation in conjugated polymer/fullerene heterostructures

被引：1
|
作者：
Markov, DE [1 ]
Amsterdam, E [1 ]
Blom, PWM [1 ]
Sieval, AB [1 ]
Hummelen, JC [1 ]
机构：
[1] Univ Groningen, Ctr Mat Sci Plus, NL-9747 AG Groningen, Netherlands
来源：
ORGANIC OPTOELECTRONICS AND PHOTONICS | 2004年 / 5464卷
关键词：
conjugated polymer; exciton diffusion; charge transport;
D O I：
10.1117/12.546041
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
Time-resolved luminescence spectroscopy has been used to investigate exciton diffusion in thin films of poly(p-phenylene vinylene) (PPV) based derivatives. Exciton density distribution upon photoexcitation in polymer/fullerene heterostructures has been modeled and exciton diffusion length values of 5 nm and 6 nm are estimated for two different PPV derivatives, which differ by three orders of magnitude in charge carrier mobility due to reduced energetic disorder. Hence, the exciton diffusion length is not correlated to the charge carrier mobility in this class of materials.
引用
收藏
页码：449 / 454
页数：6
相关论文
共 50 条
  • [1] Exciton diffusion and dissociation in conjugated polymer fullerene blends and heterostructures
    Haugeneder, A
    Neges, M
    Kallinger, C
    Spirkl, W
    Lemmer, U
    Feldmann, J
    Scherf, U
    Harth, E
    Gügel, A
    Müllen, K
    [J]. PHYSICAL REVIEW B, 1999, 59 (23): : 15346 - 15351
  • [2] Hot exciton dissociation in a conjugated polymer
    Arkhipov, VI
    Emelianova, EV
    Bässler, H
    [J]. PHYSICAL REVIEW LETTERS, 1999, 82 (06) : 1321 - 1324
  • [3] Control of electron transfer in conjugated polymer/fullerene heterostructures
    Kallinger, C.
    Hauder, M.
    Haugeneder, A.
    Lemmer, U.
    Spirkl, W.
    Feldmann, J.
    Scherf, U.
    Harth, E.
    Gügel, A.
    Müllen, K.
    [J]. Synthetic Metals, 1999, 101 (01): : 285 - 286
  • [4] Photoinduced electron transfer in conjugated polymer/fullerene heterostructures
    Haugeneder, A
    Kallinger, C
    Spirkl, W
    Lemmer, U
    Feldmann, J
    Scherf, U
    Harth, E
    Gugel, A
    Mullen, K
    [J]. FULLERENES AND PHOTONICS IV, 1997, 3142 : 140 - 147
  • [5] Control of electron transfer in conjugated polymer fullerene heterostructures
    Kallinger, C
    Hauder, M
    Haugeneder, A
    Lemmer, U
    Spirkl, W
    Feldmann, J
    Scherf, U
    Harth, E
    Gügel, A
    Müllen, K
    [J]. SYNTHETIC METALS, 1999, 101 (1-3) : 285 - 286
  • [6] Nanomechanical Imaging of the Diffusion of Fullerene into Conjugated Polymer
    Wang, Dong
    Nakajima, Ken
    Liu, Feng
    Shi, Shaowei
    Russell, Thomas P.
    [J]. ACS NANO, 2017, 11 (09) : 8660 - 8667
  • [7] Exciton dissociation dynamics in a conjugated polymer containing aggregate states
    Haugeneder, A
    Lemmer, U
    Scherf, U
    [J]. CHEMICAL PHYSICS LETTERS, 2002, 351 (5-6) : 354 - 358
  • [8] ONE-DIMENSIONAL EXCITON DIFFUSION IN A CONJUGATED POLYMER
    RUGHOOPUTH, SDDV
    BLOOR, D
    PHILLIPS, D
    MOVAGHAR, B
    [J]. PHYSICAL REVIEW B, 1987, 35 (15) : 8103 - 8112
  • [9] Homocoupling Defects in a Conjugated Polymer Limit Exciton Diffusion
    Streiter, Martin
    Beer, Daniel
    Meier, Fabian
    Goehler, Clemens
    Lienert, Caroline
    Lombeck, Florian
    Sommer, Michael
    Deibel, Carsten
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2019, 29 (46)
  • [10] Probing coherent ultrafast exciton dissociation in a polymer: fullerene photovoltaic absorber
    De Sio, Antonietta
    Sommer, Ephraim
    Maiuri, Margherita
    Rehault, Julien
    Rozzi, Carlo Andrea
    Molinari, Elisa
    Cerullo, Giulio
    Lienau, Christoph
    [J]. 2015 CONFERENCE ON LASERS AND ELECTRO-OPTICS (CLEO), 2015,
12345