Photoinduced Bending Behavior of Cross-linked Azobenzene Liquid-Crystalline Polymer Films with a Poly(oxyethylene) Backbone

被引：28
|
作者：
Lv, Jiu-an [1 ,2 ]
Wang, Weiru [3 ]
Xu, Jixiang [1 ,2 ]
Ikeda, Tomiki [4 ]
Yu, Yanlei [1 ,2 ]
机构：
[1] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
[2] Fudan Univ, State Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China
[3] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[4] Chuo Univ, Res & Dev Initiat, Bunkyo Ku, Tokyo 1128551, Japan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2014年 / 35卷 / 14期
基金：
中国国家自然科学基金;
关键词：
azobenzene; liquid-crystalline polymers; photoinduced bending; photoinitiated cationic polymerization; LIGHT-INDUCED DEFORMATION; PHOTOMECHANICAL RESPONSE; UNBENDING BEHAVIOR; MAIN-CHAIN; ELASTOMERS; ACTUATORS; GLASSY; DRIVEN; PHOTODRIVEN; GELS;
D O I：
10.1002/marc.201400112
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Cross-linked azobenzene liquid-crystalline polymer films with a poly(oxyethylene) backbone are synthesized by photoinitiated cationic copolymerization. Azobenzene moieties in the film surface toward the light source are simultaneously photoaligned during photopolymerization with unpolarized 436 nm light and thus form a splayed alignment in the whole film. The prepared films show reversible photoinduced bending behavior with opposite bending directions when different surfaces of one film face to ultraviolet light irradiation.
引用
收藏
页码：1266 / 1272
页数：7
相关论文
共 50 条
  • [1] Location of the Azobenzene Moieties within the Cross-Linked Liquid-Crystalline Polymers Can Dictate the Direction of Photoinduced Bending
    Priimagi, Arri
    Shimamura, Aki
    Kondo, Mizuho
    Hiraoka, Tomohiro
    Kubo, Shoichi
    Mamiya, Jun-Ichi
    Kinoshita, Motoi
    Ikeda, Tomiki
    Shishido, Atsushi
    [J]. ACS MACRO LETTERS, 2012, 1 (01): : 96 - 99
  • [2] Precisely direction-controllable bending of cross-linked liquid-crystalline polymer films by light
    Yu, YL
    Nakano, M
    Maeda, T
    Kondo, M
    Ikeda, T
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2005, 436 : 1235 - 1244
  • [3] Photoinduced bending behavior of crosslinked liquid-crystalline polymer films with a long spacer
    Zhang, Yuanyuan
    Xu, Jixiang
    Cheng, Futao
    Yin, Ruoyuan
    Yen, Chu-Chun
    Yu, Yanlei
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (34) : 7123 - 7130
  • [4] Effect of cross-linking density on photoinduced bending behavior of oriented liquid-crystalline network films containing azobenzene
    Yu, YL
    Nakano, M
    Shishido, A
    Shiono, T
    Ikeda, T
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (09) : 1637 - 1643
  • [5] Simultaneous Analysis of Optical and Mechanical Properties of Cross-Linked Azobenzene-Containing Liquid-Crystalline Polymer Films
    Shimamura, Aid
    Priimagi, Arri
    Mamiya, Jun-ichi
    Ikeda, Tomiki
    Yu, Yanlei
    Barrett, Christopher J.
    Shishido, Atsushi
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (11) : 4190 - 4196
  • [6] Photoinduced deformation Behavior of crosslinked azobenzene liquid-crystalline polymer films with unimorph and bimorph structure
    Kondo, Mizuho
    Mamiya, Jun-ichi
    Kinoshita, Motoi
    Ikeda, Tomiki
    Yu, Yanlei
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2007, 478 : 1001 - 1013
  • [7] Photoinduced deformation and isomerization of azobenzene liquid-crystalline polymer films at cryogenic temperature
    Ogikubo, Shunya
    Hashimoto, Gaku
    Ube, Toru
    Suda, Masayuki
    Yamamoto, Hiroshi
    Ikeda, Tomiki
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2018, 676 (01) : 30 - 35
  • [8] PREPARATION OF ORDERED, CROSS-LINKED AND THERMALLY STABLE LIQUID-CRYSTALLINE POLY(VINYL ETHER) FILMS
    ANDERSSON, H
    GEDDE, UW
    HULT, A
    [J]. POLYMER, 1992, 33 (19) : 4014 - 4018
  • [9] Photomobile Polymer Materials: Photoresponsive Behavior of Cross-Linked Liquid-Crystalline Polymers with Mesomorphic Diarylethenes
    Mamiya, Jun-ichi
    Kuriyama, Akito
    Yokota, Naoki
    Yamada, Munenori
    Ikeda, Tomiki
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (08) : 3174 - 3177
  • [10] CREEP-BEHAVIOR OF CHEMICALLY CROSS-LINKED HYDROXYPROPYL CELLULOSE FILMS WITH LIQUID-CRYSTALLINE ORDER
    SUTO, S
    SUZUKI, K
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 63 - CELL
12345