Copper-Catalyzed Cascade Bicyclization of o-Alkenylphenyl Isothiocyanates with Sodium Azide Leading to the 5H-Benzo[d]tetrazolo[5,1-b][1,3]thiazines

被引：1
|
作者：
Zhang, Yahui [1 ]
Liu, Yang [1 ]
Miao, Jiankang [1 ]
Hao, Wenyan [1 ]
机构：
[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Key Lab Funct Small Organ Mol, Minist Educ, Nanchang 330022, Jiangxi, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 40卷 / 08期
基金：
中国国家自然科学基金;
关键词：
copper-catalysis; cascade bicyclization; 5H-benzo[d]tetrazolo[5,1-b][1,3]thiazine; o-alkenylphenyl isothiocyanate; ONE-POT SYNTHESIS; BETA-LACTAMS; ENANTIOSELECTIVE SYNTHESIS; EFFICIENT SYNTHESIS; BOND FORMATION; C-S; 5-SUBSTITUTED; 1H-TETRAZOLES; STEREOSELECTIVE-SYNTHESIS; 3-COMPONENT SYNTHESIS; KINUGASA REACTION;
D O I：
10.6023/cjoc201912036
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and efficient method for the preparation of 5H-benzo[d]tetrazolo[5,1-b][1,3]thiazines has been developed. The transformation involved the copper(I)-catalyzed cascade bicyclization of o-alkenylphenyl isothiocyanates with sodium azide to afford corresponding products in moderate to good yields. This present strategy provides an effective way to construct small molecular N-, and S-heterocycles.
引用
收藏
页码：2426 / 2432
页数：7
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