Volatile complexes of Nb(IV) with new sterically hindered β-diketones

被引：0
|
作者：
Kandybin, MV [1 ]
Belaya, SV
Malkova, VI
Nadolinnyi, VA
Semyannikov, PP
Igumenov, IK
Zanina, AS
Shergina, SI
Sokolov, IE
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
[2] Russian Acad Sci, Inst Chem Kinet & Combust, Siberian Div, Novosibirsk, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 1999年 / 69卷 / 06期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of niobium tetraiodide with sterically hindered beta-diketones in the presence of diethylamine gave eight-coordinate Nb(IV) complexes Nb(beta-diket)(4). The thermal stability of the complexes at atmospheric pressure and in a vacuum and the nature of the hydrolysis and oxidation products were studied. The possibility of using the complexes as precursors for preparing Nb(IV) oxide layers was examined.
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页码：866 / 875
页数：10
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