A {Co32} Nanosphere Supported by p-tert-Butylthiacalix[4]arene

被引：250
|
作者：
Bi, Yanfeng [1 ,3 ]
Wang, Xiu-Teng [2 ]
Liao, Wuping [1 ]
Wang, Xiaofei [1 ,3 ]
Wang, Xinwu [1 ]
Zhang, Hongjie [1 ]
Gao, Song [2 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 33期
关键词：
SINGLE-MOLECULE MAGNETS; CLUSTER COMPLEXES; TRANSITION-METAL; ANISOTROPY; CHEMISTRY; WHEEL;
D O I：
10.1021/ja9034939
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Calixarene-capped Co-32 clusters are constructed by a sodalite Co-24(II) cage and an encapsulated Co-8(III) cube. The spherical units are arranged into three isomeric structures, two of which are stacked by the bcc lattices and the third of which is assembled by the cubic closest packing of the spherical units.
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收藏
页码：11650 / +
页数：3
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