5-(3-quinolinylthio)methyl-tetrahydro-2-furanones from 3,3′-bis(4-substituted quinolinyl)disulfides

被引:0
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作者
Marciniec, K [1 ]
Maslankiewicz, A [1 ]
Boryczka, S [1 ]
机构
[1] Med Univ Silesia, Dept Organ Chem, PL-41200 Sosnowiec, Poland
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The intramolecular lactonization of 4-pentenoic acid to the title tetrahydrofuranones (12) was performed by addition of electrochemically generated sulfenyl cations starting from 3,3'-bis(4-substituted quinolinyl) disulfides (7a, b, c, d, e) and 3,3'-bis(1-methyl-1,4-dihydro-4-oxo-quinolinyl) disulfide (9b) and using bromide as a redox catalyst. Two syntheses of diquinolinyl disulfide (7e) were described as well.
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页码:1279 / +
页数:9
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