Effects of Different Surfactants on the Kinetics of Ethane-Hydrate Formation: Experimental and Modeling Studies

被引:20
|
作者
Karimi, Reza [1 ]
Varaminian, Farshad [1 ]
Izadpanah, Amir A. [2 ]
Mohammadi, Amir H. [3 ,4 ]
机构
[1] Semnan Univ, Dept Chem Engn Oil & Gas, Semnan, Iran
[2] Persian Gulf Univ, Gas & Petrochem Engn Fac, Bushehr, Iran
[3] Inst Rech Genie Chim & Petr, Paris, France
[4] Univ KwaZulu Natal, Sch Chem Engn, Thermodynam Res Unit, ZA-4041 Durban, South Africa
关键词
clathrates; ethane; gas hydrates; kinetics; surfactants; UNSTIRRED GAS/LIQUID SYSTEM; NATURAL-GAS; METHANE; STORAGE; GROWTH;
D O I
10.1002/ente.201300064
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
An experimental study of the ethane-hydrate-formation kinetics has been performed. First, the effects of stirring velocity and initial pressure on the hydrate-formation rate were investigated. Second, the effects of additives on the ethane-hydrate-formation rate were also studied. Three surfactants, namely sodium dodecylbenzenesulfonate (SDBS), dodecyl trimethyl ammonium bromide (DTAB), and TritonX-100 (TX-100) were tested. The results show that DTAB not only does not significantly promote the hydrate-formation rate at different concentrations, but actually inhibits the ethane-hydrate-formation rate, whereas SDBS does increase the hydrate-formation rate. Furthermore, TX-100 increases the ethane-hydrate-formation rate, but to a lesser degree than SDBS.
引用
收藏
页码:530 / 536
页数:7
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