Electrodeposition and characterization of NiCoP

被引:10
|
作者
Mondal, Kanchan [1 ]
Sathithsuksanoh, Noppodan [2 ]
Lalvani, Shashi B. [1 ,3 ]
机构
[1] Southern Illinois Univ, Dept Mech Engn & Energy Proc, Carbondale, IL 62901 USA
[2] Univ Louisville, Dept Chem Engn, Louisville, KY 40292 USA
[3] Miami Univ, Dept Chem Paper & Biomed Engn, Oxford, OH 45056 USA
来源
SN APPLIED SCIENCES | 2020年 / 2卷 / 12期
关键词
Electrodeposition; Corrosion; Amorphous; Hardness; characterization; X-ray diffraction; HYDROGEN EVOLVING ACTIVITY; IRON-NICKEL ALLOYS; NI-P; ANOMALOUS CODEPOSITION; MAGNETIC-PROPERTIES; CURRENT-DENSITY; MEDIA NOISE; FILMS; MODEL; WEAR;
D O I
10.1007/s42452-020-03921-6
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The influence of the mass transfer effects, the applied current density, the solution pH and temperature, and bath composition on the current efficiency of the deposit was determined. Cyclic voltammetry on the deposition bath was conducted to understand the mechanism of deposition. The films were characterized by x-ray diffraction spectroscopy and were found to be generally amorphous with small amounts of crystalline phases dispersed depending upon the phosphorous content. The corrosion resistance of the deposits in a chloride medium was observed to increase with the phosphorous content. The knoop hardness of the electrodeposits was studied as a function of the phosphorous content as well.
引用
收藏
页数:12
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