A new site-isolated acid-base bifunctional metal-organic framework for one-pot tandem reaction

被引：59
|
作者：
Lee, Yu-Ri [1 ]
Chung, Young-Min [2 ]
Ann, Wha-Seung [1 ]
机构：
[1] Inha Univ, Dept Chem & Chem Engn, Inchon 402751, South Korea
[2] Kunsan Natl Univ, Dept Nano & Chem Engn, Kunsan 573701, Jeollabuk Do, South Korea
来源：
RSC ADVANCES | 2014年 / 4卷 / 44期
基金：
新加坡国家研究基金会;
关键词：
POST-SYNTHETIC MODIFICATION; CATALYSIS; LIGAND; AMINE; MOFS;
D O I：
10.1039/c4ra02683g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly porous and stable acid-base bifunctional metal-organic framework, MIL-101-NH2-SO3H, was prepared by direct solvothermal synthesis using two mixed (-NO2, -SO3H) terephthalate linkers followed by post-synthesis reduction to the NH2 form, which showed excellent performance for a one-pot tandem deacetalization-nitroaldol reaction.
引用
收藏
页码：23064 / 23067
页数：4
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