Catalytic reactivity of Cr/SiO2 in the liquid phase oxidation of cyclohexanol by tert-butyl hydroperoxide

被引：11
|
作者：
Parentis, ML [1 ]
Bonini, NA [1 ]
Gonzo, EE [1 ]
机构：
[1] UNSa, INIQUI, RA-4400 Salta, Argentina
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2002年 / 76卷 / 02期
关键词：
chromium catalysts; cyclohexanol oxidation; alkyl hydroperoxide;
D O I：
10.1023/A:1016523608979
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Silica supported chromium is a heterogeneous, active and selective catalyst for the liquid phase oxidation of cyclohexanol by tert-butyl hydroperoxide (TBHP) in the presence or absence of oxygen. It is also active for the decomposition of TBHP. The reactivity at 70degreesC and atmospheric pressure is higher than over other catalysts and the cyclohexanone selectivity is 100%.
引用
收藏
页码：243 / 248
页数：6
相关论文
共 50 条
  • [1] Catalytic reactivity of Cr/SiO2 in the liquid phase oxidation of cyclohexanol by tert-butyl hydroperoxide
    Monica L. Parentis
    Norberto A. Bonini
    Elio E. Gonzo
    Reaction Kinetics and Catalysis Letters, 2002, 76 : 243 - 248
  • [2] Catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol by tert-butyl hydroperoxide over Pt/oxide catalysts
    I REKKAB-HAMMOUMRAOUI
    A CHOUKCHOU-BRAHAM
    L PIRAULT-ROY
    C KAPPENSTEIN
    Bulletin of Materials Science, 2011, 34 : 1127 - 1135
  • [3] Catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol by tert-butyl hydroperoxide over Pt/oxide catalysts
    Rekkab-Hammoumraoui, I.
    Choukchou-Braham, A.
    Pirault-Roy, L.
    Kappenstein, C.
    BULLETIN OF MATERIALS SCIENCE, 2011, 34 (05) : 1127 - 1135
  • [4] Catalytic activity of MnTUD-1 for liquid phase oxidation of ethylbenzene with tert-butyl hydroperoxide
    Gaffar Imran
    Muthusamy Poomalai Pachamuthu
    Rajamanickam Maheswari
    Anand Ramanathan
    S. J. Sardhar Basha
    Journal of Porous Materials, 2012, 19 : 677 - 682
  • [5] Catalytic activity of MnTUD-1 for liquid phase oxidation of ethylbenzene with tert-butyl hydroperoxide
    Imran, Gaffar
    Pachamuthu, Muthusamy Poomalai
    Maheswari, Rajamanickam
    Ramanathan, Anand
    Basha, S. J. Sardhar
    JOURNAL OF POROUS MATERIALS, 2012, 19 (05) : 677 - 682
  • [6] LIQUID-PHASE OXIDATION OF UNDECANAL BY TERT-BUTYL HYDROPEROXIDE IN DODECANE
    MUSHRUSH, GW
    HAZLETT, RN
    EATON, HG
    INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1985, 24 (02): : 290 - 293
  • [7] LIQUID-PHASE OXIDATION OF THIOPHENE COMPOUNDS BY TERT-BUTYL HYDROPEROXIDE
    MUSHRUSH, GW
    WATKINS, JM
    HAZLETT, RN
    HARDY, DR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 41 - PETR
  • [8] Selective catalytic oxidation of organosulfur compounds with tert-butyl hydroperoxide
    Chica, A
    Gatti, G
    Moden, B
    Marchese, L
    Iglesia, E
    CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (07) : 1960 - 1967
  • [9] TETRABROMOOXOMOLYBDATE(V) COMPLEX - THE CATALYTIC REACTIVITY FOR THE REACTION OF TERT-BUTYL HYDROPEROXIDE
    KURUSU, Y
    MASUYAMA, Y
    SAITA, M
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (03) : 1065 - 1066
  • [10] Amorphous Cr/SiO2 Materials Hydrothermally Treated: Liquid Phase Cyclohexanol Oxidation
    José Feliciano Miranda
    Pablo M. Cuesta Zapata
    Elio E. Gonzo
    Mónica L. Parentis
    Lilian E. Davies
    Norberto A. Bonini
    Catalysis Letters, 2018, 148 : 2082 - 2094
12345