Viscosity and Density of Ternary Solution of Calcium Chloride plus Sodium Chloride plus Water from T = (293.15 to 323.15) K

被引:14
|
作者
Qiblawey, Hazim [1 ]
Arshad, Mohammad [1 ]
Easa, Ahmed [1 ]
Atilhan, Mert [1 ]
机构
[1] Qatar Univ, Coll Engn, Dept Chem Engn, Doha 2713, Qatar
来源
关键词
MIXED-ELECTROLYTE-SOLUTIONS; CONCENTRATION-DEPENDENCE; THERMODYNAMIC PROPERTIES; AQUEOUS-ELECTROLYTES; UNIFIED APPROACH; PREDICTION; TEMPERATURE; PRESSURE; VOLUME;
D O I
10.1021/je500070k
中图分类号
O414.1 [热力学];
学科分类号
摘要
Viscosities and densities of ternary systems of CaCl2-NaCl-water were measured in the range of T = (293.15 to 323.15) K at 5 K intervals and up to 4.5 mol.kg(-1). Two equations based on the Exponential and Goldsack and Franchetto models were applied to correlate the experimental viscosity data as a function of concentration and temperature. The optimized parameters showed that the presence of CaCl2 had a prevailing effect on the viscosity of the ternary solutions than NaCl. The dependency of the viscosity optimized parameters on temperature was investigated, too. The average absolute deviation between calculated and experimental viscosities was below 1.4 %. The work compared the above-mentioned two models to the known extended Jones Dole equation and found that both models do correlate the viscosity at higher concentrations better than the Jones Dole equation. However, the exponential model shows the superior representation for the experimental viscosity values over the other two Density data were successfully predicted with an average absolute deviation of less than 0.45 96. studied models.
引用
收藏
页码:2133 / 2143
页数:11
相关论文
共 50 条
  • [1] Viscosity and Density of the Ternary Solution of Magnesium Chloride plus Sodium Chloride plus Water from (298.15 to 318.15) K
    Qiblawey, Hazim A.
    Abu-Jdayil, Basim
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (09): : 3322 - 3326
  • [2] Density, Speed of Sound, Viscosity, and Surface Tension of Hexamethylenetetramine plus Water plus Ethanol Ternary Mixtures from T=293.15 to 323.15 K
    Gomez-Diaz, Diego
    Navaza, Jose M.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2021, 66 (05): : 2160 - 2166
  • [3] Viscosity and density of water plus sodium chloride plus potassium chloride solutions at 298.15 K
    Zhang, HL
    Han, SJ
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (03): : 516 - 520
  • [4] Density, Speed of Sound, Viscosity, and Surface Tension of Dimethylethylenediamine plus Water and (Ethanolamine plus Dimethylethanolamine) plus Water from T = (293.15 to 323.15) K
    Blanco, Antonio
    Garcia-Abuin, Alicia
    Gomez-Diaz, Diego
    Navaza, Jose M.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (01): : 188 - 194
  • [5] Isopiestic study of (calcium chloride plus water) and (calcium chloride plus magnesium chloride plus water) at T=313.15 K
    Baabor, J
    Gilchrist, MA
    Delgado, EJ
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2001, 33 (04): : 405 - 411
  • [6] Mean activity coefficients of NaCl in (sodium chloride plus sodium bicarbonate plus water) from T = (293.15 to 308.15) K
    Ji, XY
    Lu, XH
    Lin, WL
    Zhang, LZ
    Wang, YR
    Shi, J
    Lu, BCY
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2001, 33 (09): : 1107 - 1119
  • [7] Density, Speed of Sound, and Viscosity of Monoethanolamine plus Water plus N-Ethyl-2-pyrrolidone from T = (293.15 to 323.15) K
    Garcia-Abuin, Alicia
    Gomez-Diaz, Diego
    Navaza, Jose M.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2013, 58 (12): : 3387 - 3391
  • [8] Density, Speed of Sound, and Viscosity of N-Methyl-2-pyrrolidone plus Ethanolamine plus Water from T = (293.15 to 323.15) K
    Blanco, Antonio
    Garcia-Abuin, Alicia
    Gomez-Diaz, Diego
    Navaza, Jose M.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (11): : 3136 - 3141
  • [9] (Liquid plus Solid) Equilibrium, Density, and Refractive Index for (Methanol plus Sodium Chloride plus Rubidium Chloride plus Water) and (Ethanol plus Sodium Chloride plus Rubidium Chloride plus Water) at Temperatures of (288, 298, and 308) K
    Li, Shuni
    Guo, Haiyan
    Zhai, Quanguo
    Jiang, Yucheng
    Hu, Mancheng
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (11): : 3108 - 3111
  • [10] Conductivity and viscosity of 1-allyl-3-methyl-imidazolium chloride plus water and plus ethanol from 293.15 K to 333.15 K
    Xu, HT
    Zhao, DC
    Xu, P
    Liu, FQ
    Gao, G
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (01): : 133 - 135