Composition/size of the light-scattering aerosol in The Netherlands

In 1992, 1993 and 1994 the size/composition of the aerosol in The Netherlands was measured in several measuring campaigns. The central aim of the study was the characterisation of those anthropogenic particles which most effectively scatter short-wave solar radiation. Since the largest effect of aerosol on radiation was expected at the times with the highest radiative flux, the measurements were made in the summer half-year around midday and under sunny conditions. Aerosol in arctic marine air served as the reference background. It contained as little as 0.1 mu g m(-3) nitrate and non-sea-salt sulphate. In continental air some 75% of the aerosol mass was submicron. Ammonium nitrate and ammonium sulphate were the dominant (anthropogenic) aerosol species in the size range with maximum light-scattering (0.4-1.0 mu m) and, with values up to 25 mu g m(-3), almost completely of a manmade origin. The ammonium nitrate concentrations were as high as or higher than those of ammonium sulphate, while the concentration of ammonium nitrate may have been underestimated because of evaporative losses during collection, of which examples are given. The sulphate size distribution was very similar to that in the period 1982-1984, which is indicative of stability of the distribution over time. Almost half of the submicron aerosol in the relevant size range could not be identified. Elemental-carbon contributed only an estimated 10% to this mass and the submicron dust content was even smaller. It was thus concluded by inference that most of the unidentified material was organic carbon. In marine air advected over the U.K. the submicron aerosol was manmade. In the particles which most effectively scatter solar radiation natural sea-salt-chloride is substituted by manmade sulphate. This substitution greatly changes the aerosol (radiative) properties: laboratory investigations, performed as part of this study, showed that sodium sulphate is a water-free crystal, while the original sea-salt aerosols are metastable saline droplets. (C) 1997 Elsevier Science Ltd.