Molecular recognition: preparation and characterization of two tripodal anion receptors

被引：14

作者：

Shokri, Alireza ^{[1
]}

Deng, S. H. M. ^{[2
,3
]}

Wang, Xue-Bin ^{[2
,3
]}

Kass, Steven R. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[2] Pacific NW Natl Lab, Div Phys Sci, Richland, WA 99352 USA

[3] Washington State Univ, Dept Phys, Richland, WA 99354 USA

来源：

ORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 01期

基金：

美国国家科学基金会;

关键词：

DENSITY FUNCTIONALS; HYDROGEN-BONDS; BASIS-SETS; BINDING; ENERGETICS; THERMOCHEMISTRY; TRANSPORTERS; CATECHOL; FLUORIDE; FAMILY;

D O I：

10.1039/c3qo00009e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two new tripodal hydroxyl-based anion receptors (1 and 2) are reported and their 1 : 1 molecular complexes with Cl-, H2PO4-, and OAc- along with the (M - 1)(-) ion of 1 were characterized by negative ion photoelectron spectroscopy in the gas phase and by binding constant determinations in four solvents (i.e., CDCl3, CD2Cl2, CD3COCD3, and CD3CN). An intramolecular hydrogen bond network (HBN) in hexaol 1 was found to diminish its binding whereas the triol 2 is the strongest aliphatic hydroxyl-based receptor to date.

引用

页码：54 / 61

页数：8

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