Manganese-catalyzed intermolecular C-H/C-H coupling of carbonyls and heteroarenes

被引：23
|
作者：
Hattori, Keika [1 ,2 ]
Ziadi, Asraa [1 ,2 ]
Itami, Kenichiro [1 ,2 ,3 ]
Yamaguchi, Junichiro [1 ,2 ]
机构：
[1] Nagoya Univ, Inst Transformat Biomol WPI ITbM, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Dept Chem, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[3] Nagoya Univ, JST, ERATO, Itami Mol Nanocarbon Project,Chikusa Ku, Nagoya, Aichi 4648602, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 31期
关键词：
ALPHA-ARYLATION; TERMINAL ALKYNES; INDOLE; ACETATE; CYCLIZATIONS; SCOPE; ACID; DERIVATIVES; INHIBITORS; KETONES;
D O I：
10.1039/c4cc01376j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Manganese-catalyzed intermolecular C-H/C-H coupling of carbonyls and heteroarenes has been developed. The presence of NaIO4 as an oxidant is crucial for the catalytic reaction. These new, inexpensive reaction conditions allow the gram-scale synthesis of a-heteroaryl carboxylic acids.
引用
收藏
页码：4105 / 4107
页数：3
相关论文
共 50 条
  • [1] Manganese-Catalyzed C-H Amidation of Heteroarenes in Water
    Kong, Xianqiang
    Lin, Long
    Xu, Bo
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (15) : 2801 - 2805
  • [2] Manganese-Catalyzed C-H Activation
    Liu, Weiping
    Ackermann, Lutz
    [J]. ACS CATALYSIS, 2016, 6 (06): : 3743 - 3752
  • [3] Manganese-Catalyzed C-H Olefination Reactions
    Hu, Yuanyuan
    Wang, Congyang
    [J]. CHEMCATCHEM, 2019, 11 (04) : 1167 - 1174
  • [4] Manganese(I)- Catalyzed C-H Aminocarbonylation of Heteroarenes
    Liu, Weiping
    Bang, Jonas
    Zhang, Yujiao
    Ackermann, Lutz
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (47) : 14137 - 14140
  • [5] Palladium(II)-Catalyzed Oxidative C-H/C-H Cross-Coupling of Heteroarenes
    Xi, Peihua
    Yang, Fan
    Qin, Song
    Zhao, Dongbing
    Lan, Jingbo
    Gao, Ge
    Hu, Changwei
    You, Jingsong
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (06) : 1822 - +
  • [6] Manganese-catalyzed insertion of aldehydes into a C-H bond
    Kuninobu, Yoichiro
    Nishina, Yuta
    Takeuchi, Takahiro
    Takai, Kazuhiko
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (34) : 6518 - 6520
  • [7] Manganese-Catalyzed Aromatic C-H Allylation of Ketones
    Ali, Shaukat
    Huo, Jiaqi
    Wang, Congyang
    [J]. ORGANIC LETTERS, 2019, 21 (17) : 6961 - 6965
  • [8] Manganese-Catalyzed Enantioselective Benzylic C-H Azidation
    Yilitabaier, Julaiti
    Xie Jin
    [J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2022, 42 (11) : 3901 - 3902
  • [9] Pd-catalyzed oxidative C-H/C-H cross-coupling of pyridines with heteroarenes
    Liu, Bo
    Huang, Yumin
    Lan, Jingbo
    Song, Feijie
    You, Jingsong
    [J]. CHEMICAL SCIENCE, 2013, 4 (05) : 2163 - 2167
  • [10] Divergent Annulative C-C Coupling of Indoles Initiated by Manganese-Catalyzed C-H Activation
    Liu, Bingxian
    Li, Jie
    Hu, Panjie
    Zhou, Xukai
    Bai, Dachang
    Li, Xingwei
    [J]. ACS CATALYSIS, 2018, 8 (10): : 9463 - 9470
12345