Hexamethylphosphoramide as a flame retarding additive for lithium-ion battery electrolytes

被引：45
|
作者：
Izquierdo-Gonzales, S [1 ]
Li, WT [1 ]
Lucht, BL [1 ]
机构：
[1] Univ Rhode Isl, Dept Chem, Kingston, RI 02881 USA
来源：
JOURNAL OF POWER SOURCES | 2004年 / 135卷 / 1-2期
关键词：
flame retardants; lithium-ion rechargeable batteries; electrolyte;
D O I：
10.1016/j.jpowsour.2004.04.011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hexamethylphosphoramide (HMPA) was investigated as a flame retarding additive for lithium-ion batteries. The flammability, electrochemical stability, conductivity, and cycling performance of electrolytes containing HMPA were studied. The addition of HMPA to electrolytes comprising solutions of LiPF6 in organic carbonates provided a significant reduction in the flammability of the electrolyte. However, the HMPA caused a slight decrease in the conductivity and electrochemical stability window of the electrolyte. Cycling performance of coin cells containing HMPA modified electrolytes was diminished. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：291 / 296
页数：6
相关论文
共 50 条
  • [1] Dimethyl methylphosphonate (DMMP) as an efficient flame retardant additive for the lithium-ion battery electrolytes
    Xiang, H. F.
    Xu, H. Y.
    Wang, Z. Z.
    Chen, C. H.
    [J]. JOURNAL OF POWER SOURCES, 2007, 173 (01) : 562 - 564
  • [2] Allyl ethyl carbonate as an additive for lithium-ion battery electrolytes
    Lee, JT
    Lin, YW
    Jan, YS
    [J]. JOURNAL OF POWER SOURCES, 2004, 132 (1-2) : 244 - 248
  • [3] Lithium borates for lithium-ion battery electrolytes
    Lex-Balducci, Alexandra
    Schmitz, Rene
    Schmitz, Raphael Wilhelm
    Mueller, Romek Ansgar
    Amereller, Marius
    Moosbauer, Dominik
    Gores, Heiner
    Winter, Martin
    [J]. RECHARGEABLE LITHIUM-ION BATTERIES, 2010, 25 (36): : 13 - 17
  • [4] Enhanced lithium-ion transport in organosilyl electrolytes for lithium-ion battery applications
    Lyons, Leslie J.
    Beecher, Scott
    Cunningham, Evan
    Derrah, Tom
    Su, Shengyi
    Zhu, Junmian
    Usrey, Monica
    Pena-Hueso, Adrian
    Johnson, Tobias
    West, Robert
    [J]. MRS COMMUNICATIONS, 2019, 9 (03) : 985 - 991
  • [5] Enhanced lithium-ion transport in organosilyl electrolytes for lithium-ion battery applications
    Leslie J. Lyons
    Scott Beecher
    Evan Cunningham
    Tom Derrah
    Shengyi Su
    Junmian Zhu
    Monica Usrey
    Adrián Peña-Hueso
    Tobias Johnson
    Robert West
    [J]. MRS Communications, 2019, 9 : 985 - 991
  • [6] A study on sulfites for lithium-ion battery electrolytes
    Yu, Bi Tao
    Qiu, Wei Hua
    Li, Fu Shen
    Cheng, Li
    [J]. JOURNAL OF POWER SOURCES, 2006, 158 (02) : 1373 - 1378
  • [7] Flammability parameters of lithium-ion battery electrolytes
    Swiderska-Mocek, A.
    Jakobczyk, P.
    Rudnicka, E.
    Lewandowski, A.
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2020, 318
  • [8] Fluorocyanoesters as Additives for Lithium-Ion Battery Electrolytes
    Walton, Joshua J.
    Hiasa, Takumi
    Kumita, Hideyuki
    Takeshi, Kazumasa
    Sandford, Graham
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (13) : 15893 - 15902
  • [9] Silyl electrolytes for lithium-ion battery applications
    Lyons, Leslie
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [10] Thermal stability of lithium-ion battery electrolytes
    Ravdel, B
    Abraham, KM
    Gitzendanner, R
    DiCarlo, J
    Lucht, B
    Campion, C
    [J]. JOURNAL OF POWER SOURCES, 2003, 119 : 805 - 810
12345