One-Step Synthesis of Unsymmetrical N-Alkyl-N′-aryl Perylene Diimides

被引:30
|
作者
Robb, Maxwell J.
Newton, Brandon
Fors, Brett P.
Hawker, Craig J. [1 ]
机构
[1] Univ Calif Santa Barbara, Dept Mat, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
来源
JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 13期
基金
美国国家科学基金会;
关键词
ELECTRON-TRANSFER; ENERGY-TRANSFER; FLUORESCENT; DYAD; OLIGOTHIOPHENE;
D O I
10.1021/jo500945k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient and facile protocol for the synthesis of unsymmetrical N-alkyl-N'-aryl perylene diimides is reported that circumvents the need for multiple reaction steps. A number of unsymmetrical perylene diimides containing a solubilizing swallowtail alkyl group and a variety of substituted aryl groups can be prepared in a single step from a simple mixture of amines.
引用
收藏
页码:6360 / 6365
页数:6
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