Synthesis and Photochemical Characteristics of Amphiphilic Enediyne Dendrimers

被引：4

作者：

Yoshimura, Nao ^{[1
]}

Momotake, Atsuya ^{[1
]}

Shinohara, Yoshihiro ^{[2
]}

Takahashi, Kayori ^{[3
]}

Nagahata, Ritsuko ^{[3
]}

Nishimura, Yoshinobu ^{[1
]}

Arai, Tatsuo ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

[2] Univ Tsukuba, Res Facil Ctr Sci & Technol, Tsukuba, Ibaraki 3058577, Japan

[3] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2009年 / 82卷 / 06期

关键词：

STILBENE DENDRIMERS; PHOTOISOMERIZATION; ISOMERIZATION;

D O I：

10.1246/bcsj.82.723

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amphiphilic enediyne-cored dendrimers were prepared as pure cis and trans isomers. All dendrimers were flourescent to give fluorescence quantum yield of 0.10-0.64, and they underwent efficient photochemical isomerization with quantum yields of 0.22-0.50 in THF. In water, other photochemical reactions took place. Fluorescence or triplet lifetimes were also strongly affected by dendrimer generation and solvent polarity. The structure-photochemical property relationship of new photoresponsive dendrimers is discussed.

引用

页码：723 / 729

页数：7

共 50 条

[1] Photochemical properties of enediyne-cored dendrimers bearing naphthalenes at the periphery
Ichino, Rina
Momotake, Atsuya
Arai, Tatsuo
[J]. CANADIAN JOURNAL OF CHEMISTRY, 2019, 97 (02) : 112 - 119
[2] Adsorption characteristics of amphiphilic dendrimers
Lenz, Dominic A.
Blaak, Ronald
Likos, Christos N.
[J]. SOFT MATTER, 2009, 5 (15) : 2905 - 2912
[3] Photochemical Characteristics of Amphiphilic Stilbene Dendrimers Induced by Aggregate Formation at Very Low Concentration
Kataoka, Kayoko
Arai, Tatsuo
[J]. CHEMISTRY LETTERS, 2013, 42 (05) : 535 - 537
[4] Synthesis of bioactive amphiphilic dendrimers
Azagarsamy, Malar A.
Sokkalingam, Punidha
Thayumanavan, S.
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
[5] Synthesis and photoisomerization of enediyne-type dendrimers with benzyl ether dendrons
Yoshimura, Nao
Momotake, Atsuya
Shinohara, Yoshihiro
Nishimura, Yoshinobu
Arai, Tatsuo
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2007, 80 (10) : 1995 - 2000
[6] Synthesis and properties of chiral, amphiphilic dendrimers.
Parquette, JR
Laufersweiler, MJ
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U638 - U638
[7] The synthesis and photochemical properties of amphiphilic phenylazonaphthalenes
Zhang, AD
Qin, JG
[J]. SUPRAMOLECULAR SCIENCE, 1998, 5 (5-6): : 573 - 576
[8] Synthesis, aggregation, and chiroptical properties of chiral, amphiphilic dendrimers
Laufersweiler, MJ
Rohde, JM
Chaumette, JL
Sarazin, D
Parquette, JR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (19): : 6440 - 6452
[9] Synthesis of Cationic Amphiphilic Surface-Block Polyester Dendrimers
Prata, Carla A. H.
Luman, Nathanel R.
Li, Yuan
Luo, Dan
McIntosh, Thomas J.
Barthelemy, Philippe
Grinstaff, Mark W.
[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2018, 28 (02) : 383 - 398
[10] An emerging class of amphiphilic dendrimers for pharmaceutical and biomedical applications: Janus amphiphilic dendrimers
Sikwal, Dhiraj R.
Kalhapure, Rahul S.
Govender, Thirumala
[J]. EUROPEAN JOURNAL OF PHARMACEUTICAL SCIENCES, 2017, 97 : 113 - 134

← 1 2 3 4 5 →