Ionic autocatalytic reaction fronts in electric fields

被引:17
|
作者
Snita, D
Sevcikova, H
Marek, M
Merkin, JH
机构
[1] PRAGUE INST CHEM TECHNOL,DEPT CHEM ENGN,CR-16628 PRAGUE 6,CZECH REPUBLIC
[2] UNIV LEEDS,DEPT APPL MATH,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND
来源
JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 48期
关键词
D O I
10.1021/jp9613302
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The travelling waves of the front type that are initiated in a system in which there is an ionic autocatalytic reaction, with a quadratic rate law, are considered when a constant current I is applied, These waves are seen to depend on both the current and the parameter delta(B), the ratio of diffusion coefficients of autocatalyst and substrate. For delta(B) > 1 there is a transition from kinetic front waves to Kohlrausch electrophoretic fronts as I is varied. For delta(B) < 1, both kinetic waves and Kohlrausch fronts an seen as well as an additional type of wave where a much enhanced reaction takes place.
引用
收藏
页码:18740 / 18748
页数:9
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