MOFs as Adsorbents for Low Temperature Heating and Cooling Applications

被引:400
|
作者
Henninger, Stefan K. [1 ]
Habib, Hesham A. [2 ]
Janiak, Christoph [2 ]
机构
[1] Fraunhofer Inst Solare Energiesyst ISE, D-79110 Freiburg, Germany
[2] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany
关键词
METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; HYDROGEN STORAGE; WATER-ADSORPTION; CHEMISTRY; NETWORKS; SYSTEMS; PUMP;
D O I
10.1021/ja808444z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 3D metal-organic framework (MOF)(3)-{[Ni(3)(mu(3)-btc)(2)(mu(4)-btre)(2)(mu-H(2)O)(2)]center dot similar to 22H(2)O} is found to be a reversibly dehydratable-hydratable water-stable MOF material with a Large Loading spread of 210 g/kg as a candidate for solid adsorbents in heat transformation cycles for refrigeration, heat pumping, and heat storage.
引用
收藏
页码:2776 / +
页数:3
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