Microwave-assisted synthesis of rod-like CuO/TiO2 for high-efficiency photocatalytic hydrogen evolution

被引:56
|
作者
Yu, Yi-Hsien [1 ]
Chen, Ying-Pin [2 ]
Cheng, Zhengdong [1 ,3 ]
机构
[1] Texas A&M Univ, Dept Mat Sci & Engn, College Stn, TX 77843 USA
[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[3] Texas A&M Univ, Artie McFerrin Dept Chem Engn, College Stn, TX 77843 USA
关键词
CuO; TiO2; rods; Microwave-assisted synthesis; Photocatalytic; Hydrogen evolution; TIO2; WATER; CUO; CATALYST; ARRAYS;
D O I
10.1016/j.ijhydene.2015.09.115
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CuO-deposited TiO2 rod composites were prepared through a microwave-assisted green method for high efficiency hydrogen evolution. The porous CuO/TiO2 rods with crystallinity and high specific surface (249.1 m(2)/g) area were obtained as-synthesized without calcination. Hydrogen yields were proved to be significantly improved with appropriate amount of CuO deposited onto TiO2 rods. The improved photocatalytic performance was attributed to the synergistic effects of high surface area, specific energy band structure, and enhanced light harvesting at the interface of CuO and porous TiO2 rods. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:15994 / 16000
页数:7
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