Formation of point defects in alkali metal borate and alkali metal phosphate electrochromic glasses

被引：0

作者：

Khodyakov, AA ^{[1
]}

Gromov, VV ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Phys Chem, Moscow 117915, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 1999年 / 73卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An EPR analysis shows that, in gamma-irradiated Me2O-P2O5-WO3 and Me2O-B2O3-WO3 (Me = Li, Na, K, and Rb) glasses, PO32-, PO42-, BO32-,W5+, and O-2(-) point defects and atomic hydrogen (from structurally bound water) are formed. For these glasses, the radiochemical yield of atomic hydrogen increases with the alkali metal cation radius from Li to Rb.

引用

页码：1515 / 1518

页数：4

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