Enzyme-Catalyzed Transetherification of Alkoxysilanes

被引：10
|
作者：
Abbate, Vincenzo [1 ]
Brandstadt, Kurt F. [2 ]
Taylor, Peter G. [1 ]
Bassindale, Alan R. [1 ]
机构：
[1] Open Univ, Dept Chem & Analyt Sci, Milton Keynes MK7 6AA, Bucks, England
[2] Dow Corning Corp, Midland, MI 48686 USA
来源：
CATALYSTS | 2013年 / 3卷 / 01期
关键词：
enzyme; biomimetic catalysis; transetherification; alkoxysilane; BOND FORMATION; SILICA;
D O I：
10.3390/catal3010027
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report the first evidence of an enzyme-catalyzed transetherification of model alkoxysilanes. During an extensive enzymatic screening in the search for new biocatalysts for silicon-oxygen bond formation, we found that certain enzymes promoted the transetherification of alkoxysilanes when tert-butanol or 1-octanol were used as the reaction solvents.
引用
收藏
页码：27 / 35
页数：9
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