General and selective reductive amination of carbonyl compounds using a core-shell structured Co3O4/NGr@C catalyst

被引：89

作者：

Stemmler, Tobias ^{[1
]}

Westerhaus, Felix A. ^{[1
]}

Surkus, Annette-Enrica ^{[1
]}

Pohl, Marga-Martina ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse Ev, D-18059 Rostock, Germany

来源：

GREEN CHEMISTRY | 2014年 / 16卷 / 10期

关键词：

FISCHER-TROPSCH SYNTHESIS; COBALT OXIDE CATALYSTS; N-ALKYLATION; SUPPORTED PLATINUM; SECONDARY-AMINES; HYDROGENATION; ALCOHOLS; NITROARENES; OXIDATION; KETONES;

D O I：

10.1039/c4gc00536h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The application of heterogenized non-noble metal-based catalysts in selective catalytic hydrogenation processes is still challenging. In this respect, the preparation of a well-defined cobalt-based catalyst was investigated by immobilization of the corresponding cobalt(II)-phenanthroline-chelate on Vulcan XC72R carbon powder. The formed core-shell structured cobalt/cobalt oxide nanocomposites are encapsulated by nitrogen-enriched graphene layers. This promising cheap heterogeneous catalyst allows for an efficient domino reductive amination of carbonyl compounds with nitroarenes.

引用

页码：4535 / 4540

页数：6

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