Spatial Distribution Patterns and Potential Sources of Heavy Metals in Soils of a Crude Oil-Polluted Region in China

Twenty-two soil samples were collected at the subregional scale (50 km(2)) around Gudao Town, a typical oil-producing region of the Shengli Oilfield in the Yellow River Delta, China to determine the spatial distribution patterns and potential sources of heavy metals in soils of crude oil-polluted regions. The concentrations of total petroleum hydrocarbons (TPHs) and heavy metals as well as other soil properties were determined and the enrichment factor values were calculated for the heavy metals measured. Principal component analysis (PCA) and cluster analysis (CA) were used to estimate potential sources contributing to the concentrations of heavy metals in the soils. The results revealed that the soils were slightly alkaline (pH = 7.33-8.05) and high in salinity (1.43-41.30 g kg(-1)), TPHs (0.51-28.40 g kg(-1)) and organic matter (1.74-31.50 g kg(-1)). The mean concentrations of the measured heavy metals Cu, Zn, Pb, Cd, Cr, Ni and V were 18.4, 78.2, 20.8, 0.19, 56.6, 26.3 and 62.1 mg kg(-1), respectively. Although the concentrations of all the metals measured in this study were not high enough to exceed the national control standards, there was a significant enrichment of Cd in the study area and Zn and Ni were in the category of deficiency to minimal enrichment. The spatial distribution patterns of Cu, Cr, Ni and V were similar and partially affected by oil exploitation and petroleum hydrocarbon spills. Potential sources of Cr, Ni, V and Cu in the soils were both natural sources and petroleum hydrocarbon spills, while Zn, Pb and Cd were probably from anthropogenic sources such as farming activities and traffic.