Syntheses, characterization and optical properties of some copper(I) halides with 1,10-phenanthroline ligand

被引：63
|
作者：
Yu, JH
Lü, ZL
Xu, JQ [1 ]
Bie, HY
Lu, J
Zhang, X
机构：
[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2004年 / 28卷 / 08期
关键词：
D O I：
10.1039/b314974a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrothermal reactions of CuX2 or CuX with phen (1,10-phenanthroline) have resulted in the syntheses of eight compounds 1-8. In these, 1:1 adducts of CuX/phen are reported: ionic [Cu( phen)(2)][CuX2] (X=Cl 1, Br 2) and dimer [Cu2I2(phen)] 3; the trinuclear clusters [Cu3X3(phen)(2)] (X=Br 5, I 7) were first prepared and the structures can be best described as 1:1 adducts of dimers and CuX; the chain compounds 6 and 8 belong to the same series with the formula [CuX2L] (L=organic ligand), but the chain arrangement is different; the structure of 4 is yet being refined. Compounds 1-8 have a high thermal stability. The third-order nonlinear optical properties of compounds 5, 6 and 8 were investigated and all exhibit a reverse saturable absorption (alpha(2)>0) and self-defocusing performance (n(2)<0).
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页码：940 / 945
页数：6
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