Bis(ferrocenecarbaldehyde 4-methylthiosemicarbazonato-κ2N1,S)zinc(II) methanol solvate

被引：2
|
作者：
Vikneswaran, M. R. [1 ]
Teoh, Siang Guan [1 ]
Quah, Ching Kheng [2 ]
Fun, Hoong-Kun [2 ]
机构：
[1] Univ Sains Malaysia, Sch Chem Sci, Usm 11800, Penang, Malaysia
[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
CRYSTAL-STRUCTURE;
D O I：
10.1107/S1600536809030086
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Fe2Zn(C5H5)(2)(C8H9N3S)(2)]center dot CH3OH, the dihedral angles between the substituted and unsubstituted cyclopentadienyl rings are 89.34 (8) and 85.73 (9)degrees, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn-II atom at the flap. Each methanol solvent molecule is linked to three ferrocene groups via intermolecular O-H center dot center dot center dot N, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. The crystal structure is further consolidated by C-H center dot center dot center dot pi interactions.
引用
收藏
页码：M1027 / U190
页数：18
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